Houses and Reactions of Thiazole (J. Metzger and E. Vincent).
normal man made tools for Thiazole and Thiazolium Salts (G. Vernin).
Alkyl, Aryl, Aralkyl, and comparable Thiazole Derivatives (J. Aune et al.).
Thiazolecarboxylic Acids, Thiazolecarboxaldehydes, and Thiazolyl Ketones (R. Meyer).
Halo and Nitrothiazoles (L. Forlani and P. Todesco).
Chapter I houses and Reactions of Thiazole (pages 5–164): Jacques V. Metzger, Emile?Jean Vincent, Jacques Chouteau and Gilbert Mille
Chapter II common man made tools for Thiazole and Thiazolium Salts (pages 165–335): Gaston Vernin
Chapter III Alkyl, Aryl, Aralkyl, and comparable Thiazole Derivatives (pages 337–518): Jean Pierre Aune, Henri Jean?Marie Dou and Jacqueline Crousier
Chapter IV Thiazolecarboxylic Acids, Thiazolecarboxaldehydes, and Thiazolyl Ketones (pages 519–563): Roger Meyer
Chapter V Halo? and Nitrothiazoles (pages 565–585): L. Forlani and P. E. Todesco
Read or Download Chemistry of Heterocyclic Compounds: Thiazole and Its Derivatives, Part One, Volume 34 PDF
Best chemistry books
Court cases of the Intl Symposium on sturdy country Chemistry in China, held August 9-12, 2002 in Changchun, China. comprises the wonderful learn effects lately received via a large spectrum of good kingdom chemists either from China and from out of the country.
Content material: bankruptcy IX Aminopyridines (pages 1–177): Andrew S. Tomcufcik and Lee N. StarkerChapter X Pyridinecarboxylic Acids (pages 179–346): Eugene P. OlivetoChapter XI Pyridine aspect? Chain Carboxylic Acids (pages 347–507): John C. GodfreyChapter XII Pyridinols and Pyridones (pages 509–890): Herbert Meislich
During this Festschrift devoted to the sixtieth birthday of Gregory S. Ezra, chosen researchers in theoretical chemistry current learn highlights on significant advancements within the box. initially released within the magazine Theoretical Chemistry bills, those amazing contributions are actually on hand in a hardcover print structure, in addition to a distinct digital variation.
- Proprietes Generales des Schemas en Groups
- Petroleum in the Marine Environment
- Products and Applications of Biopolymers
- Perkin and Kipping's Organic chemistry
- Integrative Plant Biochemistry
Additional info for Chemistry of Heterocyclic Compounds: Thiazole and Its Derivatives, Part One, Volume 34
C. Rhodanine In 1877, Nencki (22) condensing ammonium thiocyanate with chloroacetic acid, attributed the name rhodaninic acid (Rhodanindure) to the compound he obtained. H e noted the ability of rhodaninic acid to give colored derivatives with ferric salts. In 1879, Liebermann and Lange (20) demonstrated the formula of rhodaninic acid to be 39. In 1884, Nencki (70), studying the properties of rhodaninic acid, confirmed the formula proposed by Libermann and Lange (39) and noted its ability to condense with aldehydes.
Thiazole was also formed in the course of a study on the ease of decarboxylation of the three possible monocarboxylic acids derived from it (109). On the other EtO-CHCl I CH,CI OEt + N=C-S 8 \ 0 Scheme 43 hand, Asinger et al. (cf. Chapter 11) developed a general method of dehydrogenation of A-3-thiazolines that, applied to A-3-thiazoline itself, led to thiazole. More recently thiazole was obtained by photorearrangement of isothiazole (110). Various isotopically labeled thiazoles have been synthezised for physicochemical purposes: 2- and 5-deutero and 25 I.
Schemc 34 61 Properties and Reactions of Thiazole 22 In 1892, Marchesini (94) described the synthesis of 4-phenyl-2mercaptothiazole (62) by condensing bromoacetophenone with ammonium dithiocarbamate. Scheme 35 62 In 1893, Miolati (95) generalized the reaction of Marchesini to a halocarbonyl compounds. In 1896, Gabriel and Freiherr von Hirsch (96) condensed CS, with what they believed to be I-aminopropylene (2-methylaziridine) and obtained isomeric 4- and 5-methyl-2-mercaptothiazoline (63 and 64).
Chemistry of Heterocyclic Compounds: Thiazole and Its Derivatives, Part One, Volume 34 by Metzger