New PDF release: Bioorganic Chemistry Frontiers

By David R. Corey, Ronald N. Zuckermann, Peter G. Schultz (auth.), Professor H. Dugas (eds.)

ISBN-10: 3642762417

ISBN-13: 9783642762413

ISBN-10: 3642762433

ISBN-13: 9783642762437

Contents: D.R. Corey, R.N. Zuckermann, P.G. Schultz, Berkeley, CA: Hybrid Enzymes and the Sequence-Specific Cleavage of Nucleid Acids.- S.C. Zimmerman, Urbana, IL: Molecular Tweezers: man made Receptors for pi-Sandwich Complexation of fragrant Substrates.- Y. Murakami, Fukuoka, Japan; J. Kikuchi, Saga, Japan: Supramolecular Assemblies Formed with man made Peptide Lipids. sensible types of Biomembranes and Enzymes.- A.D. Hamilton, Pittsburgh, PA: Synthetic experiences on Molecular Recognition.- J. Chin, M. Banaszczyk, V. Jubian, J.H. Kim, okay. Mrejen, Montreal: Artificial Hydrolytic Metalloenzymes: A Unified Approach.- J.-P. Sauvage, C. Dietrich-Buchecker, Strasbourg: Interlocked and Knotted earrings in Biology and Chemistry.

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1 n-Stacking: General Considerations ....................... 2 Hydrophobically Driven n-Stacking ....................... 3 Electron Donor-Acceptor Driven n-Stacking . . . . . . . . .. 4 Triply Stacked n-Complexes ........................... , . " 36 36 37 38 40 4 Complexation of Aromatic Guests by Molecular Tweezers Using n-Sandwiching . 1 Design of Molecular Tweezers ........................... 2 Synthesis of Molecular Tweezers . . . . . . .

2 Receptors That Use Only Hydrogen Bonding Forces. . . . . 3 Receptors That Use Hydrogen Bonding Forces and a Single n-Stacking Interaction . . . . . . . . . . . . . . . . . 55 55 57 58 Bioorganic Chemistry Frontiers, Vol. 2 © Springer-Verlag Berlin Heidelberg 1991 34 Steven C. 4 Receptors That Use Hydrogen Bonding Forces and n-Sandwiching . . . . . . . . . . . . . . . . . . . . 1 Introduction . . . . . . . . . . . . .

1 Design of Molecular Tweezers ........................... 2 Synthesis of Molecular Tweezers . . . . . . . . . . . . . 3 Structure of Molecular Tweezers. . . . . . . . . . . . . 4 Complexation by Molecular Tweezers. . . . . . . . . . . 45 45 46 47 50 5 Complexation of Nucleotide Bases Using Hydrogen Bonding and n-Stacking. . . . . . . . . . . . . . . . . . .. 1 Introduction...... . . . . . . . . . . . . . . . . . .. 2 Receptors That Use Only Hydrogen Bonding Forces.

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Bioorganic Chemistry Frontiers by David R. Corey, Ronald N. Zuckermann, Peter G. Schultz (auth.), Professor H. Dugas (eds.)


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