Download e-book for kindle: Advances in Chemical Physics (Wiley Series in Probability by Joshua Jortner, Raphael D. Levine, Stuart Alan Rice

By Joshua Jortner, Raphael D. Levine, Stuart Alan Rice

ISBN-10: 047106274X

ISBN-13: 9780471062745

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Acknowledgment. . . . . . . . . . . . . . . . . . . . . Referen~s. . . . . . . . . . . . . . . . . . . . . . . I. 54 54 I. INTRODUCTION The diffusion cloud (flame) technique developed by Hartel and Polanyi’, in the 1930s is one of the early methods of studying rapid bimolecular chemical reactions under pseudo-first-order, steady-state conditions. This method is the source of most measured rates for reactions of alkali metals with halogenated compounds3 and still serves as a basis for experimental4 and theoretical’ studies.

B) D. Zakheim and P. M. Johnson, J. Chem. , 68, 3644 (1978). (c) W. M. Jackson and C. S. Lin, Int. J. Chem. Kinetics, 10, 945 (1978). 11. L. Zandee, R. B. Bernstein, and D. A. Lichtin, J. Chem. , 69, 3427 (1978). 12. S. C. Wallace, in Tunable h e r s and Applications, A. Mooradian, T. Jaeger, and P. , Springer-Verlag, Berlin, 1976, p. 1. 13. R. T. Lynch and H. Lotem, J. Chem. , 66, 1905 (1977). 14. R. B. Hochstrasser, G. R. Meredith, and H. P. Trommsdorf, Chem. Phys. , 53, 423 (1978). 15. N. Bloembergen, Nonlinear Optics, Benjamin, New York, 1965.

Siegel, and J. Levine, Phys. , A6, 631 (1972). 'A. Lofthus and P. H. Kmpenic, J. Phys. Chem. Ref. Data, 6, 113 (1977). dR. J. Celotta, R. A. Bennett, and J. L. Hall, J. Chem. , 60, 1740 (1974). 'A. F. Gains, J. K. Kay, and F. M. Page, Trans. , 62,874 (1966). 08. 7 228 ? 23 1752 17 1882 18 Expr. APPLICATION TO NITRIC OXIDE FLUORESCENCE QUENCHING 39 The model also accounts for the trend observed in the CH,Cl,-,(x=O4) series. Introduction of one chlorine atom is expected to lead to a large increase in EA.

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Advances in Chemical Physics (Wiley Series in Probability and Mathematical Statistics) by Joshua Jortner, Raphael D. Levine, Stuart Alan Rice


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